Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
نویسندگان
چکیده
منابع مشابه
Cu-catalyzed cross-coupling reactions of epoxides with organoboron compounds.
A copper-catalyzed cross-coupling reaction of epoxides with arylboronates is described. This reaction is not limited to aromatic epoxides, because aliphatic epoxides are also suitable substrates. In addition, N-sulfonyl aziridines can be successfully converted into the products. This reaction provides convenient access to β-phenethyl alcohols, which are valuable synthetic intermediates.
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The reactivity of bis-TMS-substituted C,C-diacetylenic phosphaalkene (A(2)PA) 1 in Sonogashira-Hagihara cross-coupling reactions has been examined. The selective and successive deprotection of the two silyl groups in 1 is enabled by the steric bulk of the Mes* group which renders the acetylene trans to Mes* more reactive and thereby facilitates selective and consecutive couplings with iodoarene...
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ژورنال
عنوان ژورنال: Chemical Reviews
سال: 1995
ISSN: 0009-2665,1520-6890
DOI: 10.1021/cr00039a007